赵三根
更新日期：2016-02-24
赵三根，博士、研究员、博士生导师、国家优秀青年基金获得者、福建省B类高层次人才，兼任中国晶体学会青年委员和中国光学光电子行业协会激光应用分会青年委员、《应用化学》青年编委、《Chinese Journal of Structural Chemistry 》青年编委，入选中国科协“青年人才托举工程”（托举导师：洪茂椿 院士）、福建省杰青、福建省青年拔尖人才、中科院青促会优秀会员、中科院澳门银银河7163团队相关人才计划、中科院澳门银银河7163春苗青年人才专项等。
2012年于中科院理化技术研究所获博士学位（导师：吴以成 院士），同年进入福建物构所工作。相关成果共发表SCI论文120余篇，含 J. Am. Chem. Soc.、Angew. Chem. Int. Ed.、Nat. Commun.、Sci. Bull.、Acc. Chem. Res.、CCS. Chem.、Coord. Chem. Rev.等国际权威专业期刊第一/通讯作者论文20余篇；授权发明专利20项，含美国专利1项，PCT国际专利2项；荣获2019年度福建省自然科学奖二等奖（2/5），并被评委国际专业期刊Crystal Growth & Design的2018年度科研新锐、2016年度福建省自然科学优秀学术论文一等奖（1/1）；主持了国家优青项目、福建省重点项目、国家基金面上项目两项、国家基金青年项目、福建省杰青项目等，并作为学术骨干参与中国科学院战略性先导科技专项等，多次受邀在国内外学术会议做邀请报告。
围绕光量子功能晶体材料方向的非线性光学（NLO）晶体和双折射晶体等我国优势研究领域，聚焦量子通信、光刻、激光显示、光学频率梳等光量子信息领域对先进材料的前沿需求，取得了系列引领性创新研究成果：
a) "无铍"新思路：在国际上率先提出了"无铍"深紫外NLO晶体材料的创新思路，设计合成了系列新型无铍深紫外NLO晶体，其层间连接力相比现有实用晶体KBBF提高一个数量级以上，克服了KBBF晶体层状习性严重的难题。其中Li4Sr(BO3)2（发表于Nat. Commun., 5, 4019, 2014）和RbBa2(PO3)5（发表于J. Am. Chem. Soc., 136, 8560, 2014）被Inorg. Chem.副主编、美国休斯敦大学Halasyamani教授认为是五种最具应用前景的深紫外NLO晶体之二（见Chem. Mater. 28, 5238？5258, 2016）。
b) "非 共轭"新材料：首次提出"非 共轭深紫外NLO材料"的概念，发展了其"局域极性诱导组装"策略，成功创制了多种性能优良的非 共轭深紫外NLO材料，开拓了氟磷硅酸盐等深紫外NLO材料新体系，并生长了英寸级单晶，为其实际应用奠定了基础。其中氟磷硅酸盐工作被美国科技新闻网站Phys.org以“研究发现首例非中心对称结构的氟磷硅酸盐”为题专门报道，并在福建省杰青项目结题时被专家组评为“达到了该领域国际领先水平”。
c）光量子新应用：发现了多种超大双折射率晶体材料，并揭示了其性能增益的新机制，部分材料兼具优异的NLO性能，有望拓展材料在量子通信、光子调制器、偏振光子器件、结构光场学等领域的重大应用。
招生专业：无机化学；材料物理与化学；材料与化工
研究方向：光量子功能晶体材料
联系电话：0591-63213127
Email：zhaosangen@fjirsm.ac.cn；zh3g@163.com
办公地点：中科院澳门银银河7163综合楼709，福建省福州市高新大道8号？
代表性论文:
1) Yanqiang Li, Weiqi Huang, Yang Zhou, Xianyu Song, Jieyu Zheng, Han Wang, Yipeng Song, Minjuan Li, Junhua Luo, Sangen Zhao,* A High-Performance Nonlinear Optical Crystal with a Building Block Containing Expanded -Delocalization, Angew. Chem. Int. Ed., 61, e202215145, 2022.
2) Yanqiang Li, Xu Zhang, Yang Zhou, Weiqi Huang, Yipeng Song, Han Wang, Minjuan Li, Maochun Hong, Junhua Luo, Sangen Zhao,* An Optically Anisotropic Crystal with Large Birefringence Arising from Cooperative Orbitals, Angew. Chem. Int. Ed., 61, e202208811, 2022.
3) Minjuan Li, Xu Zhang, Zheyao Xiong, Yanqiang Li, Yang Zhou, Xin Chen, Yipeng Song, Maochun Hong, Junhua Luo, Sangen Zhao,* A Hybrid Antiperovskite with Strong Linear and Second-Order Nonlinear Optical Responses, Angew. Chem. Int. Ed. 61, e202211151, 2022.
4) Weiqi Huang, Xu Zhang, Yanqiang Li, Yang Zhou, Xin Chen, Xiaoqi Li, Fafa Wu, Maochun Hong, Junhua Luo, Sangen Zhao,* A Hybrid Halide Perovskite Birefringent Crystal, Angew. Chem. Int. Ed. 61, e202202746, 2022.
5) Yang Zhou, Xu Zhang, Maochun Hong, Junhua Luo, Sangen Zhao,* Achieving effective balance between bandgap and birefringence by confining -conjugation in an optically anisotropic crystal, Sci. Bull., 67, 2276-2279, 2022.
6) Yanqiang Li, Junhua Luo,* Sangen Zhao,* Local Polarity-Induced Assembly of Second-Order Nonlinear Optical Materials, Acc. Chem. Res., 55，3460-3469, 2022.
7) Yanqiang Li, Zhengyang Zhou, Sangen Zhao,* Fei Liang, Qingran Ding, Junliang Sun,* Zheshuai Lin, Maochun Hong, Junhua Luo,* A Deep-UV Nonlinear Optical Borosulfate with Incommensurate Modulations, Angew. Chem. Int. Ed. 60, 11457, 2021.
8) Youchao Liu, Youquan Liu, Zheshuai Lin, Yanqiang Li, Qingran Ding, Xin Chen, Lina Li, Sangen Zhao,* Maochun Hong and Junhua Luo, Nonpolar Na10Cd(NO3)4(SO3S)4 Exhibits a Large Second-Harmonic Generation, CCS Chem., 4, 526–531, 2022.
9) Youchao Liu, Xiaomeng Liu, Shuai Liu, Qingran Ding, Yanqiang Li, Lina Li, Sangen Zhao,* Zheshuai Lin, Junhua Luo, Maochun Hong, An Unprecedented Antimony(III) Borate with Strong Linear and Nonlinear Optical Responses, Angew. Chem. Int. Ed., 59, 7793, 2020.
10) Shuai Liu,# Xiaomeng Liu,# Sangen Zhao,* Youchao Liu, Lina Li, Qingran Ding, Yanqiang Li, Zheshuai Lin,* Junhua Luo, Maochun Hong, An exceptional peroxide birefringent material resulting from d- interactions, Angew. Chem. Int. Ed., 59, 9414, 2020.
11) Qingran Ding, Xiaomeng Liu, Sangen Zhao,* Yusong Wang, Yanqiang Li, Lina Li, Shuai Liu, Zheshuai Lin, Maochun Hong, Junhua Luo,* Designing a Deep-UV Nonlinear Optical Fluorooxosilicophosphate, J. Am. Chem. Soc., 142, 6472, 2020.
12) Yanqiang Li, Congling Yin, Xiaoyan Yang, Xiaojun Kuang,* Jie Chen, Lunhua He, Qingran Ding, Sangen Zhao,* Maochun Hong and Junhua Luo,* A Nonlinear Optical SwitchableSulfate of Ultrawide Bandgap, CCS Chem., 2, 2298, 2020.
13) Yanqiang Li, Fei Liang, Sangen Zhao,* Lina Li, Zhenyue Wu, Qingran Ding, Shuai Liu, Zheshuai Lin,* Maochun Hong, and Junhua Luo,* Two Non- -Conjugated Deep-UV Nonlinear Optical Sulfates, J. Am. Chem. Soc., 141, 3833？3837, 2019.
14) Zhao, Sangen; Yang, Xiaoyan; Yang, Yi; Kuang, Xiaojun;* Lu, Fengqi; Shan, Pai; Sun, Zhihua, Lin, Zheshuai;* Hong, Maochun; Luo, Junhua,* Non-Centrosymmetric RbNaMgP2O7 with Unprecedented Thermo-Induced Enhancement of Second Harmonic Generation, J. Am. Chem. Soc., 140, 1592, 2018.
15) Sangen Zhao, Yi Yang, Yaoguo Shen, Bingqing Zhao, Lina Li, Chengmin Ji, Zhenyue Wu, Daqiang Yuan, Zheshuai Lin,* Maochun Hong, and Junhua Luo,* Cooperation of Three Chromophores Generates the Water-Resistant Nitrate Nonlinear Optical Material Bi3TeO6OH(NO3)2, Angew. Chem. Int. Ed. 56, 540–544, 2017.
16) Sangen Zhao, Lei Kang, Yaoguo Shen, Xiaodong Wang, Muhammad Adnan Asghar, Zheshuai Lin,* Yingying Xu, Siyuan Zeng, Maochun Hong, and Junhua Luo,* Designing a Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material without a Structural Instability Problem, J. Am. Chem. Soc. 138, 2961-2964, 2016.
17) Sangen Zhao, Pifu Gong, Siyang Luo, Sijie Liu, Lina, Li, Muhammad Adnan Asghar, Tariq Khan, Maochun Hong, Zheshuai Lin, and Junhua Luo,* Beryllium-Free Rb3Al3B3O10F with Reinforced Interlayer Bonding as a Deep-Ultraviolet Nonlinear Optical Crystal, J. Am. Chem. Soc. , 137, 2207-2210, 2015.
18) Sangen Zhao, Pifu Gong, Siyang Luo, Lei Bai, Zheshuai Lin,* Yuanyuan Tang, Yuelan Zhou, Maochun Hong, and Junhua Luo,* Tailored Synthesis of a Nonlinear Optical Phosphate with a Short Absorption Edge, Angew. Chem. Int. Ed., 54, 4217-4221, 2015.
19) Sangen Zhao, Pifu Gong, Xiang Xu, Shuquan Zhang, Zhihua Sun, Zheshuai Lin,* Maochun Hong, Chuangtian Chen, Junhua Luo,* Beryllium-free Li4Sr(BO3)2 for deep-ultraviolet nonlinear optical applications, Nat. Commun., 5, 4019, 2014.
20) Sangen Zhao, Pifu Gong, Siyang Luo, Lei Bai, Zheshuai Lin,* Chenming Ji, Tianliang Chen, Maochun Hong, and Junhua Luo,* Deep-Ultraviolet Transparent Phosphates RbBa2(PO3)5 and Rb2Ba3(P2O7)2 Show Nonlinear Optical Activity from Condensation of [PO4]3- Units, J. Am. Chem. Soc., 136, 8560-8563, 2014.